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51.
Synthesis of Bi2WO6/Bi2O3 Composite with Enhanced Photocatalytic Activity by a Facile One‐step Hydrothermal Synthesis Route 下载免费PDF全文
Tianye Wang Fengjun Zhang Guosheng Xiao Shuang Zhong Cong Lu 《Photochemistry and photobiology》2015,91(2):291-297
In this study, the characterization and photocatalytic activity of Bi2WO6/Bi2O3 under visible‐light irradiation was investigated in detail. The results suggested that Bi2WO6/Bi2O3 can be synthesized by a facile one‐pot hydrothermal route using a super big 200 mL Teflon‐lined autoclave with optimal sodium oleate/Bi molar ratio of 1.25. Through the characterization of Bi2WO6/Bi2O3 by X‐ray diffraction, scanning electron microscopy, X‐ray photoelectron spectroscopy, Fourier transform infrared, UV‐vis diffuse reflectance spectra and Photoluminescence spectra, it was found that the as‐prepared composite possessed smaller crystallite size and higher visible‐light responsive than the pure Bi2WO6. Moreover, it was expected that the as‐prepared composites exhibited enhanced photocatalytic activity for the degradation of Rhodamine B under visible‐light irradiation, which could be ascribed to their improved light absorption property and the reduced recombination of the photogenerated electrons and holes during the photocatalytic reaction. In general, this study could provide a principle method to synthesize Bi2WO6/Bi2O3 with enhanced photocatalytic activity by one‐step hydrothermal synthesis route for environmental purification. 相似文献
52.
Three mono-, bi- and tetranuclear copper(I) complexes, [Cu(phen)(triphos-O)]BF4 (1) (phen = 1,10-phenanthroline, triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane), [Cu2(bipy)(triphos)2](BF4)2 (2) (bipy = 4,4′-bipyridine), and [Cu4(MeOC^N^N)4(triphos)2(bipy)](BF4)4 (3) (MeOC^N^N = 6-(4-methoxyphenyl)-2,2′-bipyridine), have been synthesized and characterized by NMR spectroscopy, electrospray ionization, and matrix-assisted laser desorption ionization time-of-flight mass spectrometries, elemental analysis, and X-ray crystal analysis. The crystal structure investigation revealed the copper ions of the complexes have pseudo-tetrahedral coordination geometry. The electronic absorption spectra of 1, 2, and 3 contain low-energy bands at 350–500 and 400–650 nm, which are assigned to d(Cu) → π*(phen or bipy) and a mixture of d(Cu) → π*(MeOC^N^N) and d(Cu) → π*(bipy) transitions, respectively. Complex 2 displays a strong, long-lived solid-state emission with a maximum at 555 nm and lifetime of 13.6 μs at room temperature. Photoinduced electron-transfer properties of 2 and 3 involving nanosecond time-resolved absorption spectroscopy and electron spin resonance techniques were studied. 相似文献
53.
A new fluorescent quenching method for the determination of phosphoproteins by using calconcarboxylic acid 下载免费PDF全文
Zhongxin Zhu Xinliang Zhu Jiayi Shen Ayi Zhou Maowei Ni Litai Jin Weitao Cong 《Electrophoresis》2015,36(6):924-929
A fluorescent quenching detection method for phosphoproteins in SDS‐PAGE by using calconcarboxylic acid (CCA) was described. In this method, the fluorescence intensity of CCA was greatly increased with the presence of Al3+ in the gel background, while in zones where phosphoproteins are located this intensity was absent because of fluorescence quenching phenomenon through the formation of CCA‐Al3+‐phosphoprotein appended complex. Approximately 4–8 ng of phosphoproteins can be selectively detected within 1 h (1D SDS‐PAGE), which is similar to that of the most commonly used Pro‐Q Diamond stain. The specificity of this novel technique for phosphoproteins was confirmed by dephosphorylation, Western blot, and LC‐MS/MS analysis, respectively. Furthermore, to better understand the newly developed method, the detection mechanism of CCA stain was explored by fluorescent spectrometry. According to the results, it is believed that CCA stain may provide a new choice for selective, economical, MS compatible, and convenient visualization of gel‐separated phosphoproteins. 相似文献
54.
In this work, a flame-retardant polypropylene(PP)/ramie fiber(RF) composite was prepared. The ramie fibers were wrapped chemically by a phosphorus- and nitrogen-containing flame retardant(FR) produced via in situ condensation reaction so as to suppress their candlewick effect. Fourier transform infrared spectroscopy(FTIR), X-ray photoelectron spectroscopy(XPS) and scanning electron microscopy(SEM) demonstrated that the ramie fibers wrapped chemically by FR(FR-RF) were obtained successfully. Thermogravimatric test showed that the PP/FR-RF composite had more residue and better thermal stability at high temperatures than the PP/RF composite. Cone calorimeter(CC) results indicated that the peak of heat release rate(PHRR) and total heat release(THR) correspondingly decreased by 23.4% and 12.5% compared with the values of neat PP/RF. The PP/FR-RF composite created a continuous and compact char layer after the combustion. Combining FTIR analysis of char residue after CC test with heat conduction coefficient results, it could be concluded that the charring of FR on RF greatly weakened the candlewick effect of RF, and more char residue in the RF domain facilitated the formation of more continuous and compact char layer in the whole combustion zone, consequently protected PP composites during combustion, resulting in the better flame retardancy of PP/FR-RF composite than that of PP/RF composite. 相似文献
55.
56.
建立了用铝基体火花源原子发射光谱仪现有通道硬件测定镁合金(MB1)中锰元素含量的方法.方法线性相关系数为0.967 6,RSD为1.66%.对8个未知样品进行了测试,结果与化学分析方法所得结果一致. 相似文献
57.
Improving the impact property and heat‐resistance of PLA/PC blends through coupling molecular chains at the interface 下载免费PDF全文
The influences of both the molecular structure and the melt viscosity differences between Poly(lactic acid) (PLA) and polycarbonate (PC) on the interpenetration of molecular chains at the interface were investigated by comparing the dynamic mechanical properties and morphologies of the as‐prepared PLA/PC solution‐casting blends with those of their corresponding annealed (180°C, 8 h) samples or PLA/PC melt blends. Additionally, two chain extenders containing epoxy groups (ADR and TGDDM) were used to improve the interfacial strength. Subsequently, the interpenetration of PLA and PC molecular chains at the interface was also surveyed. Finally, the effects of the morphology formed by after adding ADR or TGDDM on the impact property, and heat resistance were discussed. The results showed that there was no interpenetration of molecular chains at the interface in PLA/PC melt blends because of the serious hindrance of the molecular structure and the melt viscosity differences. Although the interfacial strength achieved significant increase after adding ADR or TGDDM, the increase of the interfacial strength should be caused by the connection of ADR or TGDDM molecules with PLA and PC molecules at the interface through chemical bonds rather than the entanglements of PLA and PC molecular chains because of no interpenetration of PLA and PC molecular chains at the interface. Thus, the morphology formed after adding ADR or TGDDM is still the type of complete phase separation, which may be the most suitable morphology for achieving high impact and heat resistance PLA/PC blends because these two properties strongly depend on the crystallinity of PLA phase. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
58.
High Catalytic Activity of Nitrogen and Sulfur Co‐Doped Nanoporous Graphene in the Hydrogen Evolution Reaction 下载免费PDF全文
Dr. Yoshikazu Ito Weitao Cong Dr. Takeshi Fujita Prof. Zheng Tang Prof. Mingwei Chen 《Angewandte Chemie (International ed. in English)》2015,54(7):2131-2136
Chemical doping has been demonstrated to be an effective way to realize new functions of graphene as metal‐free catalyst in energy‐related electrochemical reactions. Although efficient catalysis for the oxygen reduction reaction (ORR) has been achieved with doped graphene, its performance in the hydrogen evolution reaction (HER) is rather poor. In this study we report that nitrogen and sulfur co‐doping leads to high catalytic activity of nanoporous graphene in HER at low operating potential, comparable to the best Pt‐free HER catalyst, 2D MoS2. The interplay between the chemical dopants and geometric lattice defects of the nanoporous graphene plays the fundamental role in the superior HER catalysis. 相似文献
59.
60.
A numerical method based on radial basis function networks (RBFNs) for solving steady incompressible viscous flow problems (including Boussinesq materials) is presented in this paper. The method uses a ‘universal approximator’ based on neural network methodology to represent the solutions. The method is easy to implement and does not require any kind of ‘finite element‐type’ discretization of the domain and its boundary. Instead, two sets of random points distributed throughout the domain and on the boundary are required. The first set defines the centres of the RBFNs and the second defines the collocation points. The two sets of points can be different; however, experience shows that if the two sets are the same better results are obtained. In this work the two sets are identical and hence commonly referred to as the set of centres. Planar Poiseuille, driven cavity and natural convection flows are simulated to verify the method. The numerical solutions obtained using only relatively low densities of centres are in good agreement with analytical and benchmark solutions available in the literature. With uniformly distributed centres, the method achieves Reynolds number Re = 100 000 for the Poiseuille flow (assuming that laminar flow can be maintained) using the density of , Re = 400 for the driven cavity flow with a density of and Rayleigh number Ra = 1 000 000 for the natural convection flow with a density of . Copyright © 2001 John Wiley & Sons, Ltd. 相似文献